Pyridine N-oxide complexes of rare earth perchlorates
نویسندگان
چکیده
منابع مشابه
Rare-earth metal hydroxylamide complexes.
The rare-earth metal hydroxylamide compound Y[N(SiHMe2)2]2[ONBn2][THF] (1) was prepared by the silylamide elimination pathway from the reaction of N,N-dibenzylhydroxylamine, Bn2NOH (Bn = CH2C6H5), with Y[N(SiHMe2)2]3[THF]2 and was characterised by multinuclear NMR spectroscopy and elemental analysis. The compounds [Cp2Y(ONBn2)]2 (2a) [Cp2Sm(ONBn2)]2 (2b) were obtained by the reactions of MCp3 (...
متن کاملRare Earth and Actinide Complexes
Stephen M. Mansell 1,* and Stephen T. Liddle 2,* 1 Institute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK 2 School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK * Correspondences: [email protected] (S.M.M.); [email protected] (S.T.L.); Tel.: +44-131-451-4299 (S.M.M.); +44-161-27...
متن کامل2-(Benzylsulfanyl)pyridine N-oxide
In the title compound, C(12)H(11)NOS, the dihedral angle between the oxopyridinium and phenyl rings is 58.40 (1)°. The crystal structure is stabilized by C-H⋯O hydrogen bonds, π-π stacking inter-actions involving the pyridinium rings [centroid-centroid distance = 3.6891 (9) Å] and C-H⋯π inter-actions.
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für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
متن کاملRare earth β-diketonate and carboxylate metal complexes as precursors for MOCVD of oxide films
Volatile and thermostable complexs of lanthanide acetylacetonates and pivalates were obtained and investigated by different methods. These compounds were used for lanthanide oxide containing film producing and for fabrication of silica optical fibers doped by lanthanide oxide. The properties of these and already known volatile precursors are compared. It is well recognized that rare earth conta...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1967
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v67-036